Reverse magnetic anomaly controlled by Permian Igneous rocks in the Iberian Chain (N Spain)

Two important reverse dipolar magnetic anomalies in the Iberian Chain (Spain) are located over Permian igneous rocks. A detailed study of one of them, the Loscos magnetic anomaly, where the geological structure is well constrained, reveals that the source of the anomaly must be a reverse remanent magnetisation carried by igneous rocks, acquired during the period of the Kiaman reverse magnetic superchron. Magnetic and gravimetric detailed survey (with 50 new gravimetric measurements and 8 main magnetic profiles -six of them N–S and the rest E–Wwith a total length of 40km), together with a study of the petrophysical characteristics of igneous materials, data processing and interpretation (upward continuation, 2.5D modelling, etc.) allowed to characterize qualitatively the anomaly and its source. Two overlapping anomalies with different wavelength were identified, indicating the presence of a shallower strongly altered igneous body with heterogeneous magnetic properties, and a deeper, large igneous body, responsible for the main, long-wavelength anomaly

Diachronous folding and cleavage in an intraplate setting (Central High Atlas, Morocco) determined through the study of remagnetizations

Remagnetizations are common in intraplate basins. When remagnetizations occur at an intermediate stage between different tectonic processes, they can be used for paleo-geometrical reconstructions and relative dating of different structures. This has a particular interest in geological frameworks where other geological time markers are absent. In order to apply this methodology, it is necessary to calculate the regional remagnetization direction and subsequently to use this reference direction to restore the attitude of the beds at the moment of remagnetization acquisition. In this work, we use this methodology for dating a pervasive cleavage (whose time of formation is controversial) and the associated structures in the Central High Atlas (Morocco). Paleomagnetic directions from 64 sites were used to calculate the remagnetization direction (D = 330.9°, I = 35.1°, A/n = 6.107) which is coincident with the Albian-Cenomanian (ca. 100 M.a.) expected direction for NW Africa. This direction was used to restore the Mesozoic paleo-geometry of beds allowing us to analyze bedding orientation, cleavage and folding relationships between the present day and the Cretaceous geometry. After restoration we conclude that the development of cleavage post-dates remagnetization, being in relation with Cenozoic basin inversion. However, the paleo-geometry shows incipient folds at Cretaceous times, which can be related to an intra-Mesozoic compressional event

Capsaicin affects the structure and phase organization of phospholipid membranes

AbstractCapsaicin is a natural compound with pharmacological and toxicological effects, which given its hydrophobicity, can influence the structure of membranes. The interaction of capsaicin with model membranes of dipalmitoylphosphatidylcholine and dielaidoylphosphatidylethanolamine has been studied by using differential scanning calorimetry, fluorescent probe spectroscopy and 31P-nuclear magnetic resonance. Capsaicin remarkably affects the phase transition of dipalmitoylphosphatidylcholine, shifting the transition temperature to lower values, and giving rise, at relatively high capsaicin concentrations, to the appearance of two peaks in the thermogram. These peaks may correspond to separated phases as indicated by the partial phase diagram. Whereas capsaicin did not affect the fluorescence polarization of the probes diphenylhexatriene and trimethylammonium-diphenylhexatriene, it clearly affected that of the probe 2-anthroyloxystearic acid, indicating that the perturbation produced by capsaicin on the membrane would be mainly at the position where this fluorophore is located. On the other hand, capsaicin, at relatively low concentrations, gives rise to immiscible phases in the presence of dielaidoylphoshatidylethanolamine and decrease the temperature of the lamellar to hexagonal HII phase transition. At concentrations of capsaicin higher than 0.3 mol fraction, isotropic phases were detected. The possible implications of the effects of capsaicin on biological membranes are discussed

Magnetic extractions and electronic microscopy observations in Jurassic remagnetized carbonates

IX Congreso Geológico de España, Huelva, 12-14 de septiembre, 2016El estudio de la remagnetización en rocas carbonatadas viene realizándose durante los últimos 40 años, tanto por medio del análisis de sus propiedades magnéticas como tratando de realizar observaciones por medio de microscopía electrónica (SEM/TEM). Los resultados obtenidos con el primer análisis han proporcionado numerosos datos y hoy en día sabemos que generalmente la remagnetización es portada por magnetita. Ésta es de tamaño nanométrico generada durante la diagénesis, correspondiéndose con una remagnetización química. Sin embargo, los numerosos intentos de observación de dichos cristales por medio de SEM/TEM siempre han sido infructuosos y los cristales observados siempre presentan tamaños dentro del rango multidominio. En un nuevo intento de observación directa de dichos cristales mediante microscopía electrónica, hemos realizado nuevos ensayos sobre extractos magnéticos en calizas jurásicas remagnetizadas de las cuencas del Alto Atlas (Marruecos), Cameros y Vasco-Cantábrica (España) según las últimas técnicas propuestas en la literatura. Las propiedades magnéticas de los diferentes subproductos provenientes del proceso de extracción indican una pérdida de material magnético durante el mismo, principalmente las partículas de grano más fino (granos de tamaño monodominio y superparamagnético). Igualmente, mediante SEM/TEM únicamente han podido observarse cristales de magnetita multidominio.Since the last 40 years the analysis of remagnetized carbonates is under debate, by studying their magnetic properties and by using electronic microscopy (SEM/TEM). Results obtained from the first analyses allowed to infer that remagnetization is carried generally by nanometric magnetite and generated during the diagenesis, therefore it corresponds to a chemical remagnetization. However, several attempts to observe these magnetites by SEM/TEM were unsuccessful and in all cases the observed magnetite was in the range of multidomain size. In a new attempt to observe these crystals by electronic microscopy we did new magnetic extracts (according the last techniques proposed in the literature) in Jurassic remagnetized limestones of the High Atlas (Morocco), Cameros and Basque-Cantabrian (Spain) basins. Magnetic properties of the different sub-products of the extracts show a lost of magnetic material during the procedure, mostly of the smallest size (superparamagnetic and single-domain size). Likewise, only multi-domain magnetite grains were observed by SEM/TEM.proyecto CGL2012-38481 de la DGICyT, MINECO y fondos FEDER de la Unión Europea, así cómo por el programa de financiación de la NSF (EEUU) al Institute for Rock Magnetis

Tectonic fabrics vs. mineralogical artifacts in AMS analysis: A case study of the Western Morocco extensional Triassic basins

New magnetic fabric data from 48 sites in Upper Triassic red beds from the Argana, Asni and Tizi n''Tichka areas in the western High Atlas, in combination with rock magnetic analyses, SEM observations and qualitative chemical analyses, reveal that mineralization processes can affect the primary (extensional) or secondary (post-depositional) magnetic fabrics. Twenty out of the 48 analyzed sites show tectonic-related fabrics consistent with the rifting stage (primary). Their orientation suggests that the extensional Atlasic (for the Asni area) and Atlantic (for Argana area) distinct directions prevailing during Liassic times are already present in the Upper Triassic sediments. The other 28 sites show axes switching (including different possibilities, kmax-kmin or kint-kmin), indicating their secondary development related to mineralogical changes after deposition. However, orientation of magnetic susceptibility axes (without considering their relative value) is consistent with the main directions obtained for the rifting stage. This magnetic fabric study also suggests that (i) extension had a small transtensional component and (ii) there is a limited influence of compressional inversion tectonics

First directional European palaeosecular variation curve for the Neolithic based on archaeomagnetic data

Neolithic, Chalcolithic and Bronze Age anthropogenic cave sediments from three caves from northern Spain have been palaeomagnetically investigated. 662 oriented specimens corresponding to 39 burning events (ash–carbonaceous couplets) from the three sites with an average of 16 samples per fire were collected. 26 new archaeomagnetic directions have been obtained for the time period ranging from 5500 to 2000 yr cal. BC. These results represent the oldest archaeomagnetic directions obtained from burnt archaeological materials throughout all Western Europe. Magnetisation is carried by pseudo-single domain low-coercivity ferromagnetic minerals (magnetite, magnetite with no significant isomorphous substitution and/or maghaemite). Rock-magnetic experiments indicate a thermoremanent origin of the magnetisation although a thermochemical magnetisation cannot be excluded. Combination of the new data presented here and the recent updated Bulgarian database allows us to propose the first European palaeosecular variation (PSV) curve for the Neolithic. A bootstrap method was applied for the curve construction using penalised cubic B-splines in time. The new palaeosecular variation curve is well constrained from 6000 BC to 3700 BC, the period with the highest density of data, showing a declination maximum around 4700 BC and a minimum in inclination at 4300 BC, which are not recorded by the recent global CALS10K.1b and regional SCHA.DIF.8K models due to the use of lake sediment data. Dating resolution by using the proposed PSV curve oscillates from approximately ±30 yr to ±200 yr for the period 6000 to 1000 yr BC, reaching similar resolution as radiocarbon dating. Considering the good preservation, age-control and widespread occurrence of burnt archaeological materials across Southern Europe, they represent a new source of data for geomagnetic field modelling, as well as for archaeomagnetic dating.Published124-1371A. Geomagnetismo e PaleomagnetismoJCR Journalrestricte

pySCu: A new python code for analyzing remagnetizations directions by means of small circle utilities

The Small Circle (SC) methods are founded upon two main starting hypotheses: (i) the analyzed sites were remagnetized contemporarily, acquiring the same paleomagnetic direction. (ii) The deviation of the acquired paleomagnetic signal from its original direction is only due to tilting around the bedding strike and therefore the remagnetization direction must be located on a small circle (SC) whose axis is the strike of bedding and contains the in situ paleomagnetic direction. Therefore, if we analyze several sites (with different bedding strikes) their SCs will intersect in the remagnetization direction. The SC methods have two applications: (1) the Small Circle Intersection (SCI) method is capable of providing adequate approximations to the expected paleomagnetic direction when dealing with synfolding remagnetizations. By comparing the SCI direction with that predicted from an apparent polar wander path, the (re)magnetization can be dated. (2) Once the remagnetization direction is known, the attitude of the beds (at each site) can be restored to the moment of the acquisition of the remagnetization, showing a palinspastic reconstructuion of the structure. Some caveats are necessary under more complex tectonic scenarios, in which SC-based methods can lead to erroneous interpretations. However, the graphical output of the methods tries to avoid ‘black-box’ effects and can minimize misleading interpretations or even help, for example, to identify local or regional vertical axis rotations. In any case, the methods must be used with caution and always considering the knowledge of the tectonic frame. In this paper, some utilities for SCs analysis are automatized by means of a new Python code and a new technique for defining the uncertainty of the solution is proposed. With pySCu the SCs methods can be easily and quickly applied, obtaining firstly a set of text files containing all calculated information and subsequently generating a graphical output on the fly.CGL2012-38481 and CGL2016-77560 of the MINECO (Spanish Ministry of Economy and Competitiveness) with also FEDER founding (European Union). PC acknowledges the MINECO for the F.P.I. research grant BES-2013-062988. LT acknowledges support from National Science Foundation grant # EAR 1345003

Multidisciplinary approach to constrain kinematics of fault zones at shallow depths: a case study from the Cameros–Demanda thrust (North Spain)

Determining transport direction in thrusts is one of the main issues to study deformation and to achieve reliable balanced cross-sections reconstruction of inverted basins and thrust systems. Anisotropy of Magnetic Susceptibility provides a tool to study deformation in fault rocks through the relationships between the magnetic susceptibility ellipsoid and deformational structures. The Cameros-Demanda Thrust (N Spain) shows a relatively simple history, with an average N-directed movement during the Cenozoic, and provides the possibility of determining the relationships between magnetic fabrics and transport directions in thrusts. The outcropping rocks are Mesozoic limestones in the hangingwall of the main thrust and Cenozoic conglomerates and Albian sandstones and coal in its footwall. Illite crystallinity and organic matter maturity indicate P-T conditions on the order of....The study of AMS in fault rocks (more than 400 samples distributed in 25 sites with fault gouge, breccia and microbreccia) in the Cameros thrust and its comparison with kinematic indicators (foliation, S/C structures and slickenside striations) indicates, in spite of the a priori simple relationships inferred from thrust geometry, a complex history of movements, changing from top-to-the-NW to top-to-the-NE along the history of Cenozoic thrusting. The transport direction is either oblique to the magnetic lineation and perpendicular to the strike of magnetic foliation, and can be checked with shear structures observed in thin sections and other kinematic indicators. The results obtained indicate that AMS can give clues about the transport direction in thrusts depending on the particular structures developed in each studied area

Cholesterol and membrane phospholipid compositions modulate the leakage capacity of the swaposin domain from a potato aspartic protease (StAPs-PSI).

Potato aspartic proteases (StAPs) and their swaposin domain (StAsp-PSI) are proteins with cytotoxic activity which involves plasma membrane destabilization. The ability of these proteins to produce cell death varies with the cellular type. Therefore, StAPs and StAsp-PSI selective cytotoxicity could be attributed to the different membrane lipid compositions of target cells. In this work we investigate the possible mechanism by which StAPs and StAsp-PSI produce selective membrane destabilization. Results obtained from leakage assays show that StAsp-PSI is a potent inducer of the leakage of LUVs containing anionic phospholipids, especially those containing phosphatidylglycerol. Based in these results, we suggest that the cytotoxic activity of StAsp-PSI on pathogenic microorganisms could be mediated by the attraction between the exposed positive domains of StAsp-PSI and the negatively charged microorganism membrane. On the other hand, our circular dichroism spectroscopic measurements and analysis by size exclusion chromatography and followed by electrophoresis, indicate that hydrophobic environment is necessary to StAsp-PSI oligomerization and both StAsp-PSI disulfide bounds and membrane with negative charged phospholipids are required by StAsp-PSI to produce membrane destabilization and then induce cell death in tumors and microorganism cell targets. Additionally, we demonstrate that the presence of cholesterol into the LUV membranes strongly diminishes the capacity of StAsp-PSI to produce leakag

Reverse magnetic anomaly controlled by Permian Igneous rocks in the Iberian Chain (N Spain)

Two important reverse dipolar magnetic anomalies in the Iberian Chain (Spain) are located over Permian igneous rocks. A detailed study of one of them, the Loscos magnetic anomaly, where the geological structure is well constrained, reveals that the source of the anomaly must be a reverse remanent magnetisation carried by igneous rocks, acquired during the period of the Kiaman reverse magnetic superchron. Magnetic and gravimetric detailed survey (with 50 new gravimetric measurements and 8 main magnetic profiles -six of them N?S and the rest E?W- with a total length of 40km), together with a study of the petrophysical characteristics of igneous materials, data processing and interpretation (upward continuation, 2.5D modelling, etc.) allowed to characterize qualitatively the anomaly and its source. Two overlapping anomalies with different wavelength were identified, indicating the presence of a shallower strongly altered igneous body with heterogeneous magnetic properties, and a deeper, large igneous body, responsible for the main, long-wavelength anomaly